ASTM D7319-17 - 1.10.2017
 
Significance and Use

5.1 Sulfates and chlorides can be found in filter plugging deposits and fuel injector deposits. The acceptability for use of the fuel components and the finished fuels depends on the sulfate and chloride content.

5.2 Existent and potential inorganic sulfate and total chloride content, as measured by this test method, can be used as one measure of the acceptability of gasoline components for automotive spark-ignition engine fuel use.

 
1. Scope

1.1 This test method covers a direct injection ion chromatographic procedure for determining existent and potential inorganic sulfate and total inorganic chloride content in hydrous and anhydrous denatured ethanol and butanol to be used in motor fuel applications. It is intended for the analysis of ethanol and butanol samples containing between 1.0 mg/kg to 20 mg/kg of existent or potential inorganic sulfate and 1.0 mg/kg to 50 mg/kg of inorganic chloride.

Note 1: Tertiary butanol is not included in this test method. 1-butanol, 2-butanol, and isobutanol are included in the testing and research report for this test method.

1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Material Safety Data Sheets are available for reagents and materials. Review them for hazards prior to usage.

1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D4052-22

Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D4177-22e1

Standard Practice for Automatic Sampling of Petroleum and Petroleum Products (Includes all amendments and changes 3/24/2023).

D5827-22

Standard Test Method for Analysis of Engine Coolant for Chloride and Other Anions by Ion Chromatography

D6792-25

Standard Practice for Quality Management Systems in Petroleum Products, Liquid Fuels, and Lubricants Testing Laboratories

D6299-26

Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance

D7328-23

Standard Test Method for Determination of Existent and Potential Inorganic Sulfate and Total Inorganic Chloride in Fuel Ethanol by Ion Chromatography Using Aqueous Sample Injection

D7318-25

Standard Test Method for Existent Inorganic Sulfate in Ethanol by Potentiometric Titration

D1193-24

Standard Specification for Reagent Water