ASTM D7544-12 - 1.6.2012
 
1. Scope

1.1 This specification covers grades of pyrolysis liquid biofuel produced from biomass intended for use in various types of fuel-burning equipment under various climatic and operating conditions. These grades are described as follows:

1.1.1 Grade G is intended for use in industrial burners equipped to handle the pyrolysis liquid biofuels meeting the requirements listed for Grade G in Table 1. The pyrolysis liquid biofuel listed under Grade G in Table 1 is not intended for use in residential heaters, small commercial boilers, engines, or marine applications.

1.1.2 Grade D is intended for use in commercial/industrial burners requiring lower solids and ash content and which are equipped to handle the pyrolysis liquid biofuels meeting the requirements listed for Grade D in Table 1. The pyrolysis liquid biofuel listed under Grade D in Table 1 is not intended for use in residential heaters, engines, or marine applications not modified to handle these types of fuels.

Note 1—For information on the significance of the physical, chemical, and performance properties identified in this specification, see Appendix X1.

1.2 This specification is for use in contracts for the purchase of pyrolysis liquid biofuel and for guidance of consumers of this type of fuel.

1.3 Nothing in this specification should preclude observance of national or local regulations, which may be more restrictive.

Note 2—The generation and dissipation of static electricity may create problems in the handling of pyrolysis liquid biofuel. For more information on the subject, see Guide D4865.

1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4.1 ExceptionBTU units are included for information only in 3.1.5.1.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

TABLE 1 Detailed Requirements for Pyrolysis Liquid Biofuels

PropertyTest MethodGrade GGrade D

Gross Heat of Combustion, MJ/kg, min

D240

15

15

Water Content, % mass, max

E203

30

30

Pyrolysis Solids Content, % mass, max

D7579

2.5

0.25

Kinematic Viscosity at 40°C, mm2/s, max

D445A

125

125

Density at 20°C, kg/dm3

D4052

1.11.3

1.11.3

Sulfur Content, % mass, max

D4294

0.05

0.05

Ash Content, % mass, max

D482

0.25

0.15

pH.

E70

Report

Report

Flash Point,°C, min

D93, Procedure B

45

45

Pour Point,°C, max

D97

9

9

A Without filtering.

 
2. Referenced Documents

D6469-24

Standard Guide for Microbial Contamination in Fuels and Fuel Systems

D93-26

Standard Test Methods for Flash Point by Pensky-Martens Closed Cup Tester

D97-17b(2022)

Standard Test Method for Pour Point of Petroleum Products (Includes all amendments and changes 11/29/2022).

D240-25

Standard Test Method for Heat of Combustion of Liquid Hydrocarbon Fuels by Bomb Calorimeter

D396-26a

Standard Specification for Fuel Oils (Includes all amendments and changes 4/14/2026).

D445-24

Standard Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (and Calculation of Dynamic Viscosity)

D482-25

Standard Test Method for Ash from Petroleum Products

D4052-22

Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter

D4294-24

Standard Test Method for Sulfur in Petroleum and Petroleum Products by Energy Dispersive X-ray Fluorescence Spectrometry

D4865-23

Standard Guide for Generation and Dissipation of Static Electricity in Petroleum Fuel Systems

D5854-25

Standard Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products

D7579-25

Standard Test Method for Pyrolysis Solids Content in Pyrolysis Liquids by Filtration of Solids in Methanol

E70-24

Standard Test Method for pH of Aqueous Solutions With the Glass Electrode

E203-24

Standard Test Method for Water Using Volumetric Karl Fischer Titration