ASTM D7622-20 - 1.6.2020
 
Significance and Use

5.1The emission of mercury during crude oil refining is an environmental concern. The emission of mercury may also contaminate refined products and form amalgams with metals, such as aluminum.

5.2When representative test portions are analyzed according to this procedure, the total mercury is representative of concentrations in the sample.

 
1. Scope

1.1This test method covers the procedure to determine the total mercury content in a sample of crude oil. This test method can be used for total mercury determination in natural and processed liquid and oil products (gasoline, naphtha, etc.).

1.2This test method may be applied to samples containing between 5.0 ng/mL to 350 ng/mL of mercury. The results may be converted to mass basis.

1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4This work has been published in Determination of Mercury in Crude Oil by Atomic Spectroscopy.2

1.5WARNINGMercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Use Caution when handling mercury and mercury-containing products. See the applicable product Safety Data Sheet (SDS) for additional information. The potential exists that selling mercury or mercury-containing products, or both, is prohibited by local or national law. Users must determine legality of sales in their location.

1.6This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.7This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D1193-24

Standard Specification for Reagent Water

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D6792-25

Standard Practice for Quality Management Systems in Petroleum Products, Liquid Fuels, and Lubricants Testing Laboratories

D6300-26

Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants

D7482-17(2023)

Standard Practice for Sampling, Storage, and Handling of Hydrocarbons for Mercury Analysis

D4177-22e1

Standard Practice for Automatic Sampling of Petroleum and Petroleum Products (Includes all amendments and changes 3/24/2023).

D4175-24e1

Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants (Includes all amendments and changes 11/19/2024).

D7623-20

Standard Test Method for Total Mercury in Crude Oil Using Combustion-Gold Amalgamation and Cold Vapor Atomic Absorption Method

D6299-26

Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance