ASTM D7668-10 - 1.10.2010
 
Significance and Use

The ID and CD values and the DCN value determined by this test method provides a measure of the ignition characteristics of diesel fuel oil used in compression ignition engines.

This test can be used by engine manufacturers, petroleum refiners and marketers, and in commerce as a specification aid to relate or match fuels and engines.

The relationship of diesel fuel oil DCN determinations to the performance of full-scale, variable-speed, variable-load diesel engines is not completely understood.

This test can be applied to non-conventional diesel fuels.

This test determines ignition characteristics and requires a sample of approximately 370 mL and a test time of approximately 30 min using a fit-for-use instrument.

 
1. Scope

1.1 This test method covers the quantitative determination of the derived cetane number of conventional diesel fuel oils, diesel fuel oils containing cetane number improver additives, and is applicable to products typical of Specification D975, Grades No.1-D and 2-D regular, low and ultra-low-sulfur diesel fuel oils, European standard EN590, and Canadian standards CAN/CGSB-3.517 and CAN/CGSB3.6. The test method may be applied to the quantitative determination of the derived cetane number of blends of fuel oils containing biodiesel material (for example, Specification D975, biodiesel, and diesel fuel oil blending components.

1.2 This test method utilizes a constant volume combustion chamber with direct fuel injection into heated, compressed synthetic air. A dynamic pressure wave is produced from the combustion of the sample. An equation converts the ignition delay and the combustion delay determined from the dynamic pressure curve to a derived cetane number (DCN).

1.3 This test method covers the ignition delay ranging from 2.8 to 6.5 ms and combustion delay ranging from 5.5 to 120 ms (30.0 to 65.0 DCN). However, the precision stated only covers the range of DCN from 35 to 60.

1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D5854-25

Standard Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products

D6751-24

Standard Specification for Biodiesel Fuel Blendstock (B100) for Middle Distillate Fuels

D7467-23

Standard Specification for Diesel Fuel Oil, Biodiesel Blend (B6 to B20)

CAN/CGSB 3.6

Automotive Low-Sulphur Diesel FuelSpecification

CAN/CGSB-3.517

Regular Sulphur Diesel FuelSpecification

DIN 73372

Einspritzdsen Grsse T und U

E456-13a(2022)e1

Standard Terminology Relating to Quality and Statistics (Includes all amendments and changes 4/16/2024).

EN590

IP41

Ignition Quality of Diesel FuelsCetane Engine Test Method

D6708-24

Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material

D6299-26

Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance

D6300-26

Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants

D613-25a

Standard Test Method for Cetane Number of Diesel Fuel Oil (Includes all amendments and changes 11/6/2025).

D975-26b

Standard Specification for Diesel Fuel (Includes all amendments and changes 3/31/2026).

D1193-24

Standard Specification for Reagent Water

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D4175-24e1

Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants (Includes all amendments and changes 11/19/2024).

D4177-22e1

Standard Practice for Automatic Sampling of Petroleum and Petroleum Products (Includes all amendments and changes 3/24/2023).