ASTM D7798-13 - 1.3.2013
 
Significance and Use

5.1 The boiling range distribution of petroleum distillate fractions provides an insight into the composition of feed stocks and products related to petroleum refining processes. A major advantage of the fast analysis time obtained by this test method is increasing product through put and reduced lab testing time by a minimum factor of 3. This gas chromatographic determination of boiling range may be used to replace conventional distillation methods for control of refining operations and for product specification testing with the mutual agreement of interested parties.

5.2 Boiling range distributions obtained by this test method are essentially equivalent to those obtained by true boiling point (TBP) distillation (see Test Method D2892). They are not equivalent to results from low efficiency distillations such as those obtained with Test Method D86 or D1160.

 
1. Scope

1.1 This test method covers the determination of the boiling range distribution of petroleum products and biodiesel formulations, B5, B10, and B20. It is applicable to petroleum distillates having a final boiling point not greater than 538°C or lower at atmospheric pressure as measured by this test method. The difference between the initial boiling point and the final boiling point shall be greater than 55°C.

1.2 The test method is not applicable for analysis of petroleum distillates containing low molecular weight components (for example naphthas, reformates, gasolines, full range crude oils). Materials containing heterogeneous mixtures (for example, alcohols, ethers, acids or esters, except biodiesels) or residue are not to be analyzed by this test method. See Test Methods D3710, D7096, D6352, or D7169.

1.3 This test method uses the principles of simulated distillation methodology. This test method uses gas chromatographic components that allow the entire analysis from sample to sample to occur in 5 min or less. In these instruments the column is heated directly at rates 10–15 times that of a conventional gas chromatograph and thus the analysis time is reduced from sample to sample.

1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4.1 Exception—Appendix X1 includes temperatures in Fahrenheit for information only.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D2892-25

Standard Test Method for Distillation of Crude Petroleum (15-Theoretical Plate Column)

D6708-24

Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material

D3710-95(1999)e1

Standard Test Method for Boiling Range Distribution of Gasoline and Gasoline Fractions by Gas Chromatography

D6352-24

Standard Test Method for Boiling Range Distribution of Petroleum Distillates in Boiling Range from 174 ?C to 700 ?C by Gas Chromatography

D6300-26

Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants

D4626-23

Standard Practice for Calculation of Gas Chromatographic Response Factors

D86-23ae2

Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure (Includes all amendments and changes 11/4/2024).

D2887-24

Standard Test Method for Boiling Range Distribution of Petroleum Fractions by Gas Chromatography

D1160-24

Standard Test Method for Distillation of Petroleum Products at Reduced Pressure

E1510-95(2021)

Standard Practice for Installing Fused Silica Open Tubular Capillary Columns in Gas Chromatographs

E594-96(2026)

Standard Practice for Testing Flame Ionization Detectors Used in Gas or Supercritical Fluid Chromatography

E355-96(2021)e1

Standard Practice for Gas Chromatography Terms and Relationships (Includes all amendments and changes 4/28/2021).

D7169-23

Standard Test Method for Boiling Point Distribution of Samples with Residues Such as Crude Oils and Atmospheric and Vacuum Residues by High Temperature Gas Chromatography

D7096-25

Standard Test Method for Determination of the Boiling Range Distribution of Gasoline by Wide-Bore Capillary Gas Chromatography