ASTM D7823-13 - 1.4.2013
 
Significance and Use

5.1 Identification and quantification of phthalates: DBP, BBP, DEHP, DNOP, DINP, and DIDP are required for regulated articles. Regulations include: EU—Directive 2005/84/EC, US—Consumer Product Safety Improvement Act of 2008—section 108, Japan—Health, Labor and Welfare Ministry guideline No.336 (2010). This test method provides a procedure to identify and quantify regulated phthalates in PVC.

5.2 Other techniques successfully used to separate and identify phthalates in PVC include GC/MS, HPLC/UV, HPLC/MS, FTIR, and GC/FID (flame ionization detector).

 
1. Scope

1.1 This test method provides a procedure to identify and quantify six phthalates by thermal desorption (TD) gas chromatography (GC) mass spectrometry (MS). The phthalates are BBP, DBP, DEHP, DNOP, DINP and DIDP.

Note 1The method can be extended to include other phthalates.

1.2 Within the context of this method, “low level” is defined as 1000 ppm.

1.3 The values in SI units are to be regarded as standard.

1.4 This test method includes references, notes and footnotes that provide explanatory material. These notes and footnotes (excluding those in the tables and figures) shall not be considered as requirements of this method.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Note 2There is no known ISO equivalent to this test method.
 
2. Referenced Documents

D883-26

Standard Terminology Relating to Plastics

E177-26a

Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods (Includes all amendments and changes 5/14/2026).

E355-96(2021)e1

Standard Practice for Gas Chromatography Terms and Relationships (Includes all amendments and changes 4/28/2021).

E594-96(2026)

Standard Practice for Testing Flame Ionization Detectors Used in Gas or Supercritical Fluid Chromatography

E691-23

Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method

Practice for Use of the International System of Units (SI), the Modernized Metric System

Adjunct to Vinyl Plasticizer LibraryTotal Ion Chromatograms and Mass Spectra Available from ASTM International Headquarters. Order Adjunct No. . Original adjunct produced in 2016.

D7083-16(2022)

Standard Practice for Determination of Monomeric Plasticizers in Poly (Vinyl Chloride) (PVC) by Gas Chromatography

D1600-18

Standard Terminology for Abbreviated Terms Relating to Plastics (Withdrawn 2024)

D3465-21

Standard Guide for Purity of Monomeric Plasticizers by Gas Chromatography