ASTM D7861-14(2019) - 1.5.2019
 
Significance and Use

5.1 Biodiesel is a fuel commodity primarily used as a blending component with diesel fuel. It is important to check the concentration of biodiesel in the diesel fuel in order to make sure it is either not below the minimum allowable limit and or does not exceed the maximum allowable limit.

5.2 This test method is applicable for quality control in the production and distribution of diesel fuel and biodiesel blends.

 
1. Scope

1.1 This test method determines fatty acid methyl esters (FAME or biodiesel) in diesel fuel oils. FAME can be quantitatively determined from 1.0 % to 30.0 % by volume. This test method uses linear variable filter (LVF) array based mid-infrared spectroscopy for monitoring FAME concentration.

Note 1: See Section 6 for a list of interferences that could affect the results produced from this method.

1.2 This test method uses a horizontal attenuated total reflectance (HATR) crystal and a univariate calibration.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D1298-24

Standard Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method

D4052-22

Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D4177-22e1

Standard Practice for Automatic Sampling of Petroleum and Petroleum Products (Includes all amendments and changes 3/24/2023).

D4307-17(2021)

Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards

D975-26b

Standard Specification for Diesel Fuel (Includes all amendments and changes 3/31/2026).

D6299-26

Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance

D6300-26

Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants

D6751-24

Standard Specification for Biodiesel Fuel Blendstock (B100) for Middle Distillate Fuels

D7371-26

Standard Test Method for Determination of Biodiesel (Fatty Acid Methyl Esters) Content in Diesel Fuel Using Mid Infrared Spectroscopy (FTIR-ATR-PLS Method)

D5854-25

Standard Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products

E1655-17(2024)

Standard Practices for Infrared Multivariate Quantitative Analysis

E168-16(2023)

Standard Practices for General Techniques of Infrared Quantitative Analysis

D7467-23

Standard Specification for Diesel Fuel Oil, Biodiesel Blend (B6 to B20)