ASTM D7923-16 - 1.7.2016
 
Significance and Use

5.1 Blends of fuel ethanol and hydrocarbon have a limited solvency for water that is dependent upon temperature and the ratio of ethanol to hydrocarbon. Good handling practices are important during the blending, storage, and transportation of fuel to avoid water contamination. High concentrations of water can cause haze or phase separation in ethanol and hydrocarbon blends and lead to freezing problems at low temperatures. Water has also been associated with corrosion and filter plugging.

 
1. Scope

1.1 This test method covers the determination of water from 0.05 % to 5.0 %  by mass in blends of ethanol, hydrocarbon, and corresponding blends. It is intended for measuring water content of gasoline or other hydrocarbon blendstock, denatured fuel ethanol as cited in Specification D4806, and ethanol fuel blends such as those cited in Specification D5798 and Practice D7794. This test method is not applicable to samples that are phase separated.

1.1.1 Procedure A—For measurement of water up to 2 % by mass in ethanol and hydrocarbon blends using coulometric Karl Fischer titration. This is the referee method for samples containing up to 2 % ethanol.

1.1.2 Procedure B—For measurement of water up to 5.4 % by mass in ethanol and hydrocarbon blends using volumetric Karl Fischer titration.

1.2 This method measures mass percent water and allows for the alternative reporting of volume percent. This test method recommends the use of pyridine-free reagents.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 8.

 
2. Referenced Documents

D4806-25

Standard Specification for Denatured Fuel Ethanol

D4177-22e1

Standard Practice for Automatic Sampling of Petroleum and Petroleum Products (Includes all amendments and changes 3/24/2023).

D6708-24

Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material

D6299-26

Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance

D1152-24

Standard Specification for Methanol (Methyl Alcohol)

D4175-24e1

Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants (Includes all amendments and changes 11/19/2024).

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D1193-24

Standard Specification for Reagent Water

D5798-25

Standard Specification for Ethanol Fuel Blends for Flexible-Fuel Automotive Spark-Ignition Engines

D7794-21

Standard Practice for Blending Mid-Level Ethanol Fuel Blends for Flexible-Fuel Vehicles with Automotive Spark-Ignition Engines

E1064-24

Standard Test Method for Water in Organic Liquids by Coulometric Karl Fischer Titration

E203-24

Standard Test Method for Water Using Volumetric Karl Fischer Titration