ASTM D8006-16 - 1.3.2016
 
Significance and Use

4.1 A supply well provides groundwater for household, domestic, commercial, agricultural, or industrial uses.

4.2 Using a standardized protocol based on an existing industry standard or approved regulatory methods and procedures to collect water samples from a supply well is essential to obtain representative water quality data. These data can be critical to efforts to protect water uses, and human health, and identify changes when they occur. Use of this guide will help the project team to design and execute an effective water supply sampling program.

4.3 It is important to understand the objectives of the sampling program before designing it. Water supplies may be sampled for various reasons including any or all of the following:

(1) baseline sampling before an operation of concern,

(2) periodic sampling during such an operation,

(3) investigative responses to perceived changes in water quality, or

(4) ongoing monitoring related to known or potential groundwater constituents of concern in the area.

Sampling programs should be based on these objectives and be developed in coordination with the prospective laboratory(ies) to ensure its procedures, capabilities, and limitations meet the needs of the program, protect human health and fulfill regulatory requirements.

 
1. Scope

1.1 This guide presents a methodology for obtaining representative groundwater samples from domestic or commercial water wells that are in proximity to oil and gas exploration and production (E&P) operations. E&P operations include, but are not necessarily limited to, site preparation, drilling, completion, and well stimulation (including hydraulic fracturing), and production activities. The goal is to obtain representative groundwater samples from domestic or commercial water wells that can be used to identify the baseline groundwater quality and any subsequent changes that may be identified. While this guide focuses on baseline sampling in conjunction with oil and gas E&P activities, the principles and practices recommended are based on well-established methods that have been in use for many years in other industrial situations. This guide recommends sampling and analytical testing procedures that can identify various chemical species present including metals, dissolved gases (such as methane), hydrocarbons (and other organic compounds), as well as overall water quality.

1.2 This guide provides information on typical residential and commercial water supply well systems and guidance on developing and implementing a sampling program, including determining sampling locations, suggested purging techniques, selection of potential analyses and laboratory certifications, data management, and integrity. It also includes guidance on personal safety. The information included pertains to baseline sampling before beginning any activities that could present potential risks to local aquifers, periodic sampling during and after such work, and ongoing monitoring relating to known or potential groundwater constituents in the area. This guide does not address policy issues related to frequency or timing of sampling or sampling distances from the wellhead. In addition, it does not address reporting limits, sample preservation, holding times, laboratory quality control, regulatory action levels, or interpretation of analytical results.

1.3 These guidelines are not intended to replace or supersede regulatory requirements and technical methodology or guidance nor are these guidelines intended for inclusion by reference in regulations. Instances where this guide is in conflict with statutory or regulatory requirements, practitioners shall defer to the latter. These guidelines are intended to assist in developing sampling programs to meet project goals and objectives. However, site-specific conditions, regulatory requirements, site-specific health and safety issues, technical manuals and directives, and program data quality objectives should be evaluated and consulted along with the information contained in this guide for each individual site and sampling program.

1.4 This guide offers an organized collection of information or a series of options and does not recommend a specific course of action. This document cannot replace education or experience and should be used in conjunction with professional judgment. Not all aspects of this guide may be applicable in all circumstances. This ASTM standard is not intended to represent or replace the standard of care by which the adequacy of a given professional service must be judged, nor should this document be applied without consideration of a project’s many unique aspects. The word “Standard” in the title of this document means only that the document has been approved through the ASTM consensus process.

1.5 Users are responsible for investigating and identifying all the legal and regulatory requirements that are applicable for the location where the sampling is being performed.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D1246-16(2021)e1

Standard Test Method for Bromide Ion in Water (Includes all amendments and changes 12/6/2021).

D1293-18

Standard Test Methods for pH of Water

D1687-17(2025)

Standard Test Methods for Chromium in Water

D511-14(2021)e1

Standard Test Methods for Calcium and Magnesium In Water (Includes all amendments and changes 12/6/2021).

D512-23

Standard Test Methods for Chloride Ion In Water

D1976-20

Standard Test Method for Elements in Water by Inductively-Coupled Plasma Atomic Emission Spectroscopy

D2330-20

Standard Test Method for Methylene Blue Active Substances

D2908-91(2024)

Standard Practice for Measuring Volatile Organic Matter in Water by Aqueous-Injection Gas Chromatography

D2972-15(2023)

Standard Test Methods for Arsenic in Water

D3082-15

Standard Test Method for Boron in Water (Withdrawn 2024)

D3223-17(2025)

Standard Test Method for Total Mercury in Water

D3557-17(2025)

Standard Test Methods for Cadmium in Water

D3559-15

Standard Test Methods for Lead in Water (Withdrawn 2024)

D3648-23

Standard Practices for the Measurement of Radioactivity

D3859-15(2023)

Standard Test Methods for Selenium in Water

D3920-18

Standard Test Method for Strontium in Water

D4658-15

Standard Test Method for Sulfide Ion in Water (Withdrawn 2024)

D5673-16(2024)e1

Standard Test Method for Elements in Water by Inductively Coupled Plasma—Mass Spectrometry (Includes all amendments and changes 1/13/2025).

D5907-18

Standard Test Methods for Filterable Matter (Total Dissolved Solids) and Nonfilterable Matter (Total Suspended Solids) in Water

D5980-16(2024)

Standard Guide for Selection and Documentation of Existing Wells for Use in Environmental Site Characterization and Monitoring

D7315-17(2023)

Standard Test Method for Determination of Turbidity Above 1 Turbidity Unit (TU) in Static Mode

D7678-17(2022)

Standard Test Method for Total Oil and Grease (TOG) and Total Petroleum Hydrocarbons (TPH) in Water and Wastewater with Solvent Extraction using Mid-IR Laser Spectroscopy

D4382-18

Standard Test Method for Barium in Water, Atomic Absorption Spectrophotometry, Graphite Furnace

D516-22

Standard Test Method for Sulfate Ion in Water

D653-26

Standard Terminology Relating to Soil, Rock, and Contained Fluids

D858-17(2025)

Standard Test Methods for Manganese in Water

D888-18

Standard Test Methods for Dissolved Oxygen in Water

D1067-16(2024)

Standard Test Methods for Acidity or Alkalinity of Water

D1068-15

Standard Test Methods for Iron in Water (Withdrawn 2024)

D1125-23

Standard Test Methods for Electrical Conductivity and Resistivity of Water

D4191-15

Standard Test Method for Sodium in Water by Atomic Absorption Spectrophotometry (Withdrawn 2024)

D4192-15

Standard Test Method for Potassium in Water by Atomic Absorption Spectrophotometry (Withdrawn 2024)

D4327-17(2025)

Standard Test Method for Anions in Water by Suppressed Ion Chromatography