ASTM E200-08 - 15.12.2008
 
Significance and Use

The accuracy of many analytical measurements is dependent upon the manner in which the standard solutions are prepared and stored, and the accuracy with which they are standardized. Combining the methods recommended for the preparation and handling of such solutions into one practice eliminates the necessity for covering such details in all of the methods wherein the solutions are used.

 
1. Scope

1.1 This practice covers procedures for the preparation, standardization, and storage of the standard volumetric solutions and reagent testing solutions commonly used in chemical analysis.

1.2 The information in this practice is arranged as follows:

Sections

Referenced Documents

2

Terminology

3

Significance and Use

4

Apparatus

5

Temperature effects

6

Measurements

7

Reagents

8

Concentration of solutions

9

Mixing of solutions

10

Storage of solutions

11

Preparation and standardization of solutions

12

Precision and Bias

13

Sodium hydroxide solution, 0.02 to 1.0 meq/mL (N)

14 to 19

Hydrochloric acid, 0.02 to 1.0 meq/mL (N)

20 to 28

Sulfuric acid, 0.02 to 1.0 meq/mL (N)

29 to 33

Hydrochloric acid, special 1 meq/mL (N)

34 to 38

Sulfuric acid, special 1meq/mL (N)

39 to 43

Silver nitrate solution, 0.1 meq/mL (N)

44 to 48

Ammonium thiocyanate solution, 0.1 meq/mL (N)

49 to 53

Iodine solution, 0.1 meq/mL (N)

54 to 58

Sodium thiosulfate solution, 0.1 meq/mL (N)

59 to 63

Potassium permanganate solution, 0.1 meq/mL (N)

64 to 68

Potassium dichromate solution, 0.1 meq/mL(N)

69 to 73

Methanolic sodium hydroxide solution, 0.5 meq/mL (N)

74 to 79

Ceric sulfate solution, 0.1 meq/mL (N)

80 to 84

Acetous perchloric acid, 0.1 meq/mL (N)

85 to 89

Disodium ethylenediaminetetraacetate solution, 0.05 mol/L(M)

90 to 94

Standard ion solutions

95

Nonstandardized reagent solutions and indicator solutions

96

1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific warning statements are given throughout this practice.

 
2. Referenced Documents

E203-24

Standard Test Method for Water Using Volumetric Karl Fischer Titration

E694-18(2024)

Standard Specification for Laboratory Glass Volumetric Apparatus

Reagent Chemicals

American Chemical Society Specifications (ACS)

D1193-06(2018)

Standard Specification for Reagent Water

E50-17

Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials

E180-03

Standard Practice for Determining the Precision of ASTM Methods for Analysis and Testing of Industrial and Specialty Chemicals (Withdrawn 2009)