ASTM E2295-13 - 1.11.2013
 
Significance and Use

5.1 These methods are primarily intended to be used for the determination of silver correction in the fire assay silver determination. Silver assays are determined by fire assay for the purpose of metallurgical exchange between seller and buyer.

5.2 It is assumed that all who use this method will be trained analysts capable of performing skillfully and safely. It is expected that work will be performed in a properly equipped laboratory under appropriate quality control practices such as those described in Guide E882.

 
1. Scope

1.1 This practice covers the determination of silver corrections for fire assay of metal bearing ores, concentrates and related metallurgical materials using the spent slags and cupels from the fire assay process, by gravimetry and atomic absorption spectrophotometry.

1.2 The test methods appear in the following order:

 

Sections

Gravimetric Method

1011

Atomic Absorption Method

1213


1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. (See Practices E50 and ISO Guide 35:1989.)

 
2. Referenced Documents

E50-17

Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials

D1193-06(2018)

Standard Specification for Reagent Water

E1335-08(2017)

Standard Test Methods for Determination of Gold in Bullion by Fire Assay Cupellation Analysis

E135-23a

Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials (Includes all amendments and changes 7/17/2023).

E882-10(2016)e1

Standard Guide for Accountability and Quality Control in the Chemical Analysis Laboratory (Includes all amendments and changes 10/27/2017).

E1024-97

Standard Guide for Chemical Analysis of Metals and Metal Bearing Ores by Flame Atomic Absorption Spectrophotometry

E29-22

Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications