ASTM E2313-15 - 1.11.2015
 
Significance and Use

4.1 Knowledge of the total aldehyde content of monoethylene glycol is required to establish whether the product meets the requirements of its quality specifications.

 
1. Scope

1.1 This test method describes the spectrophotometric determination of total aldehyde content in the range of 0.5 to 50 mg/kg (as acetaldehyde) or 0.3 to 35 mg/kg (as formaldehyde) in mono-, di-, and triethylene glycol (MEG, DEG and TEG). Alkoxyalcohols (hemiacetals), if present, are co-determined, whereas dialkoxyalkanes (acetals), if present, are not. The results provide a measure of the purity of the sample with respect to total aldehyde content.

1.2 Review the current Safety Data Sheets (SDS) for detailed information concerning toxicity, first aid procedures, and safety precautions for all materials used in this test method.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D2194-22

Standard Test Method for Concentration of Formaldehyde Solutions

D6299-23a

Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance (Includes all amendments and changes 12/12/2023).

E180-03

Standard Practice for Determining the Precision of ASTM Methods for Analysis and Testing of Industrial and Specialty Chemicals (Withdrawn 2009)

D1193-06(2018)

Standard Specification for Reagent Water

E275-08(2022)

Standard Practice for Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers

E288-10(2017)

Standard Specification for Laboratory Glass Volumetric Flasks

E300-03(2022)

Standard Practice for Sampling Industrial Chemicals

Manufacturer’s Instruction Manual of Spectrophotometer

E969-02(2019)

Standard Specification for Glass Volumetric (Transfer) Pipets