ASTM E353-93(2000)e1 - 1.1.2000
 
1. Scope

1.1 These test methods cover the chemical analysis of stainless, heat-resisting, maraging, and other similar chromium-nickel-iron alloys having chemical compositions within the following limits:
ElementConcentration Range, %
Aluminum0.002 to 5.50
Boron0.001to 0.20
Carbon0.01to 1.50
Chromium0.01 to 35.00
Cobalt0.01to 15.00
Columbium (Niobium)0.01to 4.00
Copper0.01to 5.00
Lead0.001to 0.50
Manganese0.01 to 20.00
Molybdenum0.01 to 7.00
Nickel0.01to 48.00
Nitrogen0.001 to 0.50
Phosphorus0.002 to 0.35
Selenium0.01 to 0.50
Silicon0.01 to 4.00
Sulfur0.002to 0.50
Tantalum0.01 to 0.80
Tin0.001to 0.05
Titanium0.01 to 4.50
Tungsten0.01 to 4.50
Vanadium0.005 to 1.00
Zirconium0.001 to 0.20

1.2 The test methods in this standard are contained in the sections indicated below:
Sections
Aluminum, Total, by the 8-Quinolinol Gravimetric Method (0.20 to 7.00 %) 119
Aluminum, Total, by the 8-Quinolinol Photometric Method (0.003 to 0.20 %) 71
Carbon, Total, by the Combustion-Thermal Conductivity Method 2a
Carbon, Total, by the Combustion Gravimetric Method (0.05 to 1.50 %)98
Chromium by the Atomic Absorption Method (0.006 to 1.00 %)202
Chromium by the Peroxydisulfate Oxidation-Titration Method (0.10 to 35.00 %) 212
Chromium by the Peroxydisulfate-Oxidation Titrimetric Method2b
Cobalt by the Ion-Exchange-Potentiometric Titration Method (2 to 15. %) 53
Cobalt by the Nitroso-R-Salt Photometric Method (0.01 to 5.0 %)61
Copper by the Neocuproine Photometric Method (0.01 to 5.00) %) 109
Copper by the Sulfide Precipitation-Electrodeposition Gravimetric Method (0.01 to 5.00 %) 82
Lead by the Ion-Exchange-Atomic Absorption Method (0.001 to 0.50 %) 127
Manganese by the Periodate Photometric Method (0.01 to 5.00 %)8
Molybdenum by the Ion Exchange-8-Hydroxyquinoline Gravimetric Method242
Molybdenum by the Photometric Method (0.01 to 1.50 %)190
Nickel by the Dimethylglyoxime Gravimetric Method (0.1 to 48.0 %)172
Phosphorus by the Alkalimetric Method (0.02 to 0.35 %)164
Phosphorus by the Molybdenum Blue Photometric Method (0.002 to 0.35 %) 18
Silicon by the Gravimetric Method (0.05 to 4.00 %)46
Sulfur by the Gravimetric Method2c
Sulfur by the Combustion-Iodate Titration Method (0.005 to 0.5 %)37
Sulfur by the Chromatographic Gravimetric Method2b
Tin by the Solvent Extraction-Atomic Absorption Method (0.002 to 0.10 %) 180
Tin by the Sulfide-Iodometric Titration Method (0.01 to 0.05 %)90
Titanium, Total, by the Diantipyrylmethane Spectrophotometric Method (0.01 to 0.35 %)231
Vanadium by the Atomic Absorption Method (0.006 to 0.15 %)221

1.3 Test methods for the determination of several elements not included in this standard can be found in Test Methods E30 and Test Methods E1019.

1.4 Some of the concentration ranges given in 1.1 are too broad to be covered by a single test method and therefore this standard contains multiple test methods for some elements. The user must select the proper test method by matching the information given in the Scope and Interference sections of each method with the composition of the alloy to be analyzed.

1.5 The values stated in SI units are to be regarded as standard. In some cases, exceptions allowed in Practice E380 are also used.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 5 and in special "Warning" paragraphs throughout these test methods.

 
2. Referenced Documents

E350-23

Standard Test Methods for Chemical Analysis of Carbon Steel, Low-Alloy Steel, Silicon Electrical Steel, Ingot Iron, and Wrought Iron

ISO?5725

Precision of Test Methods--Determination of Repeatability and Reproducibility for Inter-Laboratory Tests Available from American National Standards Institute (ANSI), 25 W. 43rd St., 4th Floor, New York, NY 10036, www.ansi.org.

E60-11(2022)e1

Standard Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry (Includes all amendments and changes 6/29/2022).

E135-23a

Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials (Includes all amendments and changes 7/17/2023).

E173-93

Practice for Conducting Interlaboratory Studies of Methods for Chemical Analysis of Metals (Withdrawn 1997)

D1193-06(2018)

Standard Specification for Reagent Water

E29-22

Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications

E351-18

Standard Test Methods for Chemical Analysis of Cast IronĀ“All Types

E352-23

Standard Test Methods for Chemical Analysis of Tool Steels and Other Similar Medium- and High-Alloy Steels

E354-21e1

Standard Test Methods for Chemical Analysis of High-Temperature, Electrical, Magnetic, and Other Similar Iron, Nickel, and Cobalt Alloys (Includes all amendments and changes 2/23/2022).

E882-10(2016)e1

Standard Guide for Accountability and Quality Control in the Chemical Analysis Laboratory (Includes all amendments and changes 10/27/2017).

E1019-18

Standard Test Methods for Determination of Carbon, Sulfur, Nitrogen, and Oxygen in Steel, Iron, Nickel, and Cobalt Alloys by Various Combustion and Inert Gas Fusion Techniques

E1024-97

Standard Guide for Chemical Analysis of Metals and Metal Bearing Ores by Flame Atomic Absorption Spectrophotometry

E1601-19

Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method

E1806-23

Standard Practice for Sampling Steel and Iron for Determination of Chemical Composition

E50-17

Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials