ASTM E363-09 - 1.10.2009
 
Significance and Use

These test methods for the chemical analysis of metals and alloys are primarily intended to test such materials for compliance with compositional specifications such as Specification A101 and A481. It is assumed that all who use these test methods will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that work will be performed in a properly equipped laboratory.

 
1. Scope

1.1 These test methods cover the chemical analysis of chromium and ferrochromium having chemical compositions within the following limits:

Element

Concentration, %

Aluminum

0.25 max

Antimony

0.005 max

Arsenic

0.005 max

Bismuth

0.005 max

Boron

0.005 max

Carbon

9.00 max

Chromium

51.0 to 99.5

Cobalt

0.10 max

Columbium

0.05 max

Copper

0.05 max

Lead

0.005 max

Manganese

0.75 max

Molybdenum

0.05 max

Nickel

0.50 max

Nitrogen

6.00 max

Phosphorus

0.03 max

Silicon

12.00 max

Silver

0.005 max

Sulfur

0.07 max

Tantalum

0.05 max

Tin

0.005 max

Titanium

0.50 max

Vanadium

0.50 max

Zinc

0.005 max

Zirconium

0.05 max

1.2 The analytical procedures appear in the following order:

Sections

Arsenic by the Molybdenum Blue Photometric Test Method
[0.001 % to 0.005 %]

10-20

Lead by the Dithizone Photometric Test Method
[0.001 % to 0.05 %]

21-31

Chromium by the Sodium Peroxide Fusion-Titrimetric Test Method
[50 % to 75 %]

32-38

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of whoever uses this standard to consult and establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 6.

10.1 This test method covers the determination of arsenic in chromium and ferrochromium in concentrations from 0.001 % to 0.005 %.

21.1 This test method covers the determination of lead in chromium and ferrochromium in concentrations from 0.001 % to 0.05 %.

32.1 This test method covers the determination of chromium in all carbon grades of ferrochromium in concentrations from 50 % to 75 %.

 
2. Referenced Documents

A101-04(2019)

Standard Specification for Ferrochromium

E1601-19

Standard Practice for Conducting an Interlaboratory Study to Evaluate the Performance of an Analytical Method

E135-23a

Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials (Includes all amendments and changes 7/17/2023).

E60-11(2022)e1

Standard Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry (Includes all amendments and changes 6/29/2022).

E50-17

Standard Practices for Apparatus, Reagents, and Safety Considerations for Chemical Analysis of Metals, Ores, and Related Materials

E32-21

Standard Practices for Sampling Ferroalloys and Steel Additives for Determination of Chemical Composition

E29-22

Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications

A481-05(2020)

Standard Specification for Chromium Metal

E173-93

Practice for Conducting Interlaboratory Studies of Methods for Chemical Analysis of Metals (Withdrawn 1997)