ASTM E487-99 - 10.10.1999
 
1. Scope

1.1 This method covers the assessment of constant-temperature stability of chemical materials that undergo exothermic reactions. The techniques and apparatus described may be used on solids, liquids, or slurries of chemical substances.

1.2 This method is one of several developed by Committee E-27 for determining the hazards of chemical compounds and mixtures. This method is for use as a result of evidence of an exothermic reaction.

1.3 When a series of materials is tested by this method, the results permit ordering the materials relative to each other with respect to their thermal stability.

1.4 Limitations of Test :

1.4.1 This method is limited to ambient temperatures and above.

1.4.2 This method determines neither a safe storage temperature nor a safe processing temperature.

Note 1-A safe storage or processing temperature requires that any heat produced by a reaction be removed as fast as generated and that proper consideration be given to hazards associated with reaction products.

1.4.3 When this method is used to order the relative thermal stability of materials, the tests must be run under the same confinement condition (see 7.3).

1.5 This standard should be used to measure and describe the properties of materials, products, or assemblies in response to heat and flame under controlled laboratory conditions and should not be used to describe or appraise the fire hazard or fire risk of materials, products, or assemblies under actual fire conditions. However, results of this test may be used as elements of a fire risk assessment which takes into account all of the factors which are pertinent to an assessment of the fire hazard of a particular end use.

1.6 This standard may involve hazardous materials, operations, and equipment. This standard does not purport to address all of the safety problems associated with its use. It is the responsibility of whoever uses this standard to consult and establish appropriate safety and health pratices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

E537-20

Standard Test Method for Thermal Stability of Chemicals by Differential Scanning Calorimetry

E473-23b

Standard Terminology Relating to Thermal Analysis and Rheology (Includes all amendments and changes 10/5/2023).

E1445-08(2023)

Standard Terminology Relating to Hazard Potential of Chemicals

E1860-23

Standard Test Method for Elapsed Time Calibration of Thermal Analyzers

E967-18

Standard Test Method for Temperature Calibration of Differential Scanning Calorimeters and Differential Thermal Analyzers

E968-02

Standard Practice for Heat Flow Calibration of Differential Scanning Calorimeters